New Routes for Improving Hydrothermal Stability of Ordered
Mesoporous Materials and Synthesis of Mesoporous Zeolites
Feng-Shou Xiao
1
Porous Structure of SBA-15 Synthesized by Evaporation Induced Self- 9
Assembly Process
Akira Endo, Yuki Inagi and Taka0 Ohmori
Effect of the Lower Consolute Temperature on the Structure of
Mesoporous Materials
J.L. Blin, F. Michaux and M.J. Stebe
17
Tailoring Porous Silica Particle and Pore Size Using a Modified
Strober, Fink, Bohn (SFB) System and Post-Synthesis Hydrothermal
Treatment
Dona1 Keane, John Hanrahan, Mark Copley, Justin Holmes and
Michael Morris
27
2. Si-Containing Mesoporous Inorganic Frameworks
Three Dimensional Mesoporous FeSBA-1 Catalysts for Alkylation 37
and Acylation of Aromatics
Veerappan V. Balasubramanian, Josena Justus and Ajayan Vinu
Incorporation of A1 into Cage-Type Mesoporous Silica Molecular 47
Sieves
Pavuluri Srinivasu, Dhanashiri P. Sawant, Josena Justus, Veerappan
V. Balasubrumaninan and Ajayan Vinu
vii
...
Vlll
Deposition and Characterization of Functional Nanoparticles of Lead- 55
Zirconia Titanate (PZT) in Matrices of Mesoporous Silica of MCM-
48-type Structure
Vijay Narkhede and Hermann Gies
Characterization of a Germanium Analog of the Tubular
Aluminosilicate, Imogolite
Masashi Ookawa, Yoshihiro Hirao, Hiroshi Yamashita, Takashi
Maekawa and Keiichi Inukai
63
3. Mesoporous Zeolites
Synthesis of Zeolite ZSM-5 Composites with a Single Template
Jia Wang, Johan C. Groen, Marc-Olivier Coppens, Wenbo Yue and
Wuzong Zhou
71
Synthesis of Nano-Sized p-Zeolite by Dry-Gel Conversion (DGC) 79
Method without the Use of Sodium Hydroxide
Ayyamperumal Sakthivel, Akira Iida, Yoichi Nishimura, Kenichi
Komura, Yoshihiro Sugi, Sung J. Cho, Jong-Ho Kim and Gon Seo
Generation of Hierarchical Porosity in Zeolites by Seed Silanization
D.P. Serrano, J. Aguado, R. Sanz, P. Pizarro, J.M. Rodriguez,
A, Peral and I. Moreno
89
Synthesis and Characterization of Y/p Composite Zeolite and its 99
Hydrocracking Performance
Xiwen Zhang, Qun Guo, Zhizhi Zhang, Fengxiang Ling, Wanfu Sun,
and Ruifeng Li
4. Mesoporous Organosilicas
Photoresponsive Mesoporous Organosilica with Molecular Order in
the Pore Walls
Krystyna Czechura and Abdelhamid Sayari
109
Ultra-Fast Hydrothermal Synthesis of Diastereoselective Pure
Ethenylene-Bridged Periodic Mesoporous Organosilicas
Carl Vercaemst, Matthias Ide, Francis Verpoort and Pascal Van Der
Voort
ix
117
Structural Investigation of Ordered Mesoporous Silicas Functionalized
by Direct Synthesis with Cyclam Derivatives
Fabrice Gaslain, Anne-Catherine Faust, Claire Marichal,
Bknkdicte Lebeau, Yoann Rousselin, Franck Denat, Mathieu Etienne
and Alain Walcarius
129
Facile Synthesis of Free-Standing PMO Films with Amorphous and
Crystal-Like Wall Structure
Sung S. Park and Chang-Sik Ha
139
Synthesis and Characterization of Periodic Mesoporous Organosilicas
with Disulfide and Mercaptopropyl Groups
B. E. Grabicka, R. M. Grudzien, I. P. Blitz and M. Jaroniec
149
Textural Investigations of Highly Proton Conductive Functionalized
Mesoporous SiOz
Roland Marschall, Michael Wark, JiZRathouskj and Michaela
Wilhelm
159
5. Non-siliceous Inorganic Nanomaterials
Mesoporous Ceria by Structure Replication from Various Porous
Matrices
Jan Roggenbuck and Michael Tiemann
169
Synthesis of Vanadium Oxide Nanoclusters in Confined Environment
via a Template-Exchange Method
Parasuraman. Selvam, Vidya Krishna and Arunasish Layek
179
Synthesis of Co304, NiO Nanoparticles with Mesoporous Structure
and Their Electrochemical Capacitive Behaviors
Ming-Bo Zheng, Yu Zhao, Jian Cao, Jin-Song Liu, Hai-Jun Zhao,
Jie-Ming Cao, Guang-Bin Ji, Hai-Yan Wang and Jie Tao
187
X
Synthesis and Characterization of Nanoporous Co304 via
Solvothermal-Annealing Route
Hai-Jun Zhao, Ming-Bo Zheng, Dong-Mei Liu, Jing-Song Liu,
Xi-Hua Jiang, Jie Tao and Jie-Ming Cao
Synthesis of Niobia Nanostructures and their Catalytic and
Photocatalytic Activity
I. Nowak, A. Feliczak, K. Walczak, M. Darul and M. Jaroniec
6. Porous Polymers and Polymer/Inorganic Nanocomposites
Soft Microporous Frameworks Based on Oligopeptides
D. V. Soldatov
195
203
213
Mesoporous Polymers with Controlled Porosity and Functionality
Derived from Semi-Degradable Diblock Copolymers
B. Gorzolnik, J. Penelle, D. Grande, R. Sigguila, V. Mirri,
P. Davidson and R. Denoyel
225
Mesostructured Polypyrrole Synthesized by Anionic Surfactant
Templating Route
Mahasweta Nandi, Asim Bhaumik, Nawal K. Ma1 and
Masahiro Fujiwara
235
Synthesis and Characterization of Thermo-Sensitive Nanocomposite
PNIPAAm I SBA-15
Boshi Tian and Chun Yang
245
Synthesis and Preparation of Novel Polyoxometalate-Functionalized
Mesoporous Hybrid Materials
Rongfang Zhang, Chun Yang
255
Synthesis of a Microporous Organic-Inorganic Hybrid Layered
Nanocomposite with Bis(methyldichlorosilyl)biphenyl and Silicic
Acid of Ilerite
Ryo Ishii, Takuji Ikeda, Tetsuji Itoh, Toshirou Yokoyama, Taka-Aki
Hanaoka and Fuji0 Mizukami
265
xi
7. Mesoporous Carbons
Preparation of Three-Dimensionally Interconnected Ordered
Mesoporous Carbons by Using Novel Silica Nanospheres as Template
Toshiyuki Yokoi, Ryota Watanabe, Seigo Ohta, Junko. N. Kondo,
Takashi Tatsumi and Tatsuya Okubo
275
Porous Carbon MateriaIs via Chemical Vapour Deposition Using As-
Synthesised Zeolites as Template: Synthesis and Hydrogen Storage
Properties
Alexandra Pacuta and Robert Mokaya
283
Effect of Carbonisation Heating Ramp Rate on the Properties of
Ordered Mesoporous Carbons
Zhuxian Yang and Robert Mokaya
Novel Mesoporous Nitrides and Nitrogen Doped Carbon Materials
with Different Structure, Pore Diameters, and Nitrogen Contents
Ajayan Vinu
Carboxyl, Amine and Thiol Functionalized Mesoporous Carbon
Materials
Dhanashri P. Sawant, Josena Justus and Ajayan Vinu
Control of Pore Size Distribution and Conductivity of Ordered
Mesoporous Carbon
Chanho Pak, Sang H. Joo, Dae J. You, Hyuk Chang, Hyung I. Lee,
Jin H. Kim and Ji M. Kim
SBA-15-Ternplating Synthesis and Properties of Pyrrole-Based
Ordered Mesoporous Carbons
Joanna Gorka and Mietek Jaroniec
Mono and Bimodal Porosity by Pyrolysis of Block Copolymer-
Phenolic Resin Complexes
Antti Soininen, Sami Valkama, Harri Kosonen, Antti Nykanen,
Ramasubbu Ramani, Olli Ikkala, Janne Ruokolainen, Filip Tuomisto,
Peter Engelhard and Gerrit Ten Brinke
293
303
313
323
333
347
xii
Uniform Porosity in Modified Carbon Cryogels
Saghar Sepehri, Betzaida B. Garcia, Qifeng Zhang and
Guozhong Cao
Effect of Pore Morphology on the Electrochemical Properties of
Electric Double Layer Carbon Cryogel Supercapacitors
Betzaida B. Garcia, Aaron M. Feaver, Guozhong Cao, Gerald T.
Seidler, Tim T. Fister and Ken P. Nagle
8. Nanoparticles Assembly
Shaped Metal Oxide-Phosphate Composite Nanoparticles Synthesized
by Templated Disassembly
Fan Li, Sarah A. Delo and Andreas Stein
Metal Oxide Nanoparticles as Building Blocks for Periodic
Mesoporous Materials: Application in Nanotechnology
Carmela Aprile, Mercedes Alvaro and Hermenegildo Garcia
Responsive Nanoporous Organic-Inorganic Colloidal Films
Andrew K. Bohaty, Julie Cichelli, Olga Schepelina and Ilya Zharov
9. Adsorption on Nanostructured Materials
Computer Simulation Study in Adsorption of Water in Carbon
Nanotubes
Atichat Wongkoblap and Duong D. Do
Adsorptions of CH4 and C2& on MOP-28 Based Clusters:
A Combined QM and QM/MM Study
Saowapak Choomwattana, Pipat Khongpracha and Jumras Limtrakul
Effects of the Framework on the Adsorption of Methane on IRMOF-1,
IRMOF-2 and IRMOF-6 Metal-Organic Frameworks: A Combined
QM and MM Study
Bundet Boekfa, Saowapak Choornwattana, Chularat Wattanakit,
Pailin Limtrakul, Piboon Pantu, Pipat Khongpracha and Jumras
Limtrakul
355
365
377
385
395
407
423
43 1
xiii
Adsorptions of CO and NO Molecules on MOF-11: A QMMM Study
Pipat Khongpracha, Supawadee Namuangruk and Jumras Limtrakul
439
Thermal Anomaly and Molecular Motion of Organic Molecules 445
Confined in the Nanocavity of Metal-Organic Frameworks IRMOF-1
Takahiro Ueda, Kenji Kurokawa, Yoshinori Kawamura, Keisuke
Miyakubo and Taro Eguchi
10. Nanostructured Catalysts
Spray Drying: a Versatile Route for the Preparation of New Acidic
Mesostructured Powders
S. Pega, A. Coupe, C. Boissiere, T. Azais, D. Grosso, C. Sanchez,
J. Blanchard. D. Massiot and A. Chaumonnot
Lewis Acidity of Mesoporous Molecular Sieves for Acylation
Reactions
Martina Bejblovd, Josef Vlk, Dana Prochdzkovd, Helena Siklovd and
JiN cejka
Formation of Superbasic Sites under Mild Condition through
Dispersion and Redox of Neutral Potassium Nitrate Salt on Alumina
Lin B. Sun, Fang N. Gu, Ling Gao, Jing Yang, Jia H. Kou, Yuan Chun,
Ying Wang, Jian H. Zhu and Zhi G. Zou
457
477
487
Efficient and Selective Nanoporous Catalysts by Placing Multiple 497
Site-Isolated Functional Groups on Mesoporous Materials
Tewodros Asefa, Krishna K. Sharma, Abhishek Anan, Rajyalakshmi
Vathyam, Robert P. Buckley, Hieu M. Dam, Youwei Xie, Sean
Quinlivan, Gang Wang and Cole Duncan
Polymeric Activated Carbon-Supported Copper and Magnesium for
Ethylbenzene Dehydrogenation with Carbon Dioxide
Se'rgio Botelho de Oliveira, Danns Pereira Barbosa, Maria do Carmo
Range1 and Denilson Rabelo
509
xiv
Iron Oxide Magnetic Nanoparticles Confined in Mesoporous Silica
and Carbon Materials
Sher Alam, Sujit K. Mondal, Jonathan P. Hill and Ajayan Vinu
Functionalized Mesoporous Materials for Gold Catalysis
Zhen Ma, Haoguo Zhu, Wen& Yan, Steven H. Overbury and Sheng
Dai
Electrodeposition of Gold Structures in Mesoporous Ti02 Sol-Gel
Films
Inga Bannat, Kutrin Wessels, Torsten Oekermann and Michael Wark
11. Catalytic Applications of Nanoporous Materials
Mesoporous Layers of Ti02 as Highly Efficient Photocatalysts for
Clean Environment
Vit Kalousek, JiN Rathouse, Jessica Tschirch and Detlef Bahnemann
Quinoline-Carboimine Palladium Complex Immobilized on MCM-4 1
as a Versatile Catalyst for Sonogashira Cross-Coupling Reaction
Hideki Nukamura, Kenichi Komura and Yoshihiro Sugi
Soy Oil Degradation over Highly Ordered Al-MCM-41
Marcelo J.B. Souza, Gicelia Rodrigues, Antonio S. Araujo,
Anne M. G. Pedrosa and Stevie H. Lima
Biodiesel Production by Heterogeneous Catalysis in the Presence of
CaO Supported on Mesoporous Silica
M6nica C. G. Albuquerque, Diana C. S. Azevedo, Ce'lio L. Cavalcunte Jr.,
Inmaculada Jime'nez Urbistondo, Jose' Santamaria Gonzalez,
Josefa M. Me'rida Robles, Enrique Rodriguez Castellon, Antonio
Jime'nez b p e z and Pedro Maireles Torres
Polymeric Activated Carbon-Supported Vanadium and Magnesium
Oxides for Styrene Production
Raphael Dias Holtz, Maria do Carmo Range1 and Se'rgio Botelho de
Oliveira
519
529
543
553
56 1
57 1
577
589
Two Step Synthesis Procedure of Beta Zeolites: Mesoporosity and
Performance as Acidic Catalysts
Saulo de Tarso Figueiredo Grecco, Paulo Se'rgio Santana Nobre,
Ernest0 Ant6nio Urquieta-Gonzdlez and Maria do Carmo Rangel
Activated Carbon-Supported Copper-Doped Iron Oxide for
Ethylbenzene Dehydrogenation
Dannis Percira Barbosa, Maria do Carmo Rangel and Denilson
Rabelo
xv
599
607
Catalytic Properties of Platinum (11) Exchanged Zirconium Phosphate
for WGSR
Alexilda Oliveira de Souza, Maria do Carmo Rangel and Oswaldo
Luiz Alves
617
12. Environmental Applications of Nanoporous Materials
Amine-Functionalized SBA-15 Silica for the Adsorption of Carbon
Dioxide
H. Siklovd, A. Zukal, J. cejka and V. ZeleAdk
625
Adsorption of Volatile Organic Compounds on Pore Expanded
Mesoporous Materials
Rodrigo Serna-Guerrero and Abdelhamid Sayari
633
Removal of Low Vapour Pressure Toxic Substances by Nanoporous
Materials
J.M. Meneses, R. Denoyel and J. Rouquerol
643
Improvement of Mesoporous Silica as an Adsorbent for Nitrosamines
by Development of Hierarchical Structure
Fang N. Gu, Jing J. Wen, Ting T. Zhuang, Jia H. Xu, WeiHuang,
Chun F. Zhou and Jian H. Zhu
653
Application of Mesoporous Organosilicas with Sulfur- and Nitrogen-
Containing Ligands for Adsorption of Mercury Ions
Rafal M. Grudzien, Bogna E. Grabicka, Oksana Olkhovyk,
Mietek Jaroniec and Jonathan P. Blitz
665
xvi
Separation of High Surface Area Mineral Solids from Suncor Coke
Fly Ash
Abdul Majid, Steve Argue, David Kingston, Stephen Lang and James
Margeson
677
13. Bio-related Applications of Mesoporous Materials
Direct Visualization of Enzymes Encapsulated in Mesoporous
Materials
Shun-lchi Matsuura, Tetsuji Itoh, Ryo Ishii, Tatsuo Tsunoda, Satoshi
Hamakawa, Taka-Aki Hanaoka and Fujio Mizukami
687
Urease Immobilization on Pore-Expanded Mesoporous Silica and Its
Catalytic Effect on Hydrolysis of Urea
Kazi-Zukir Hossain, Abdelhamid Sayari and Carlos M. Monreal
697
Entrapment of Glucose Oxidase into Mesostructured Silica
J.L. Blin, R. Bleta, M.J. Stebe and C. Carteret
709
Influence of the Preparation Method on the Ampicillin Incorporation
in Hydrotalcite-Like Compounds
Rodica moianu, Octavian D. Pavel, Anca Cruceanu,
Mihaela Florea, Ruxandra Birjega, Andrei Rotaru, Corina Bradu and
Petre Rotaru
717
Author Index
Subject Index
729
735